Commissioning

Commissioning Failures VS Plant Performance

Commissioning & Plant Performance

Abstract

Failures in the execution of commissioning activities, like chemical cleaning or steam blowing, can go unseen for the first several months of operation, but they have the potential cause a direct impact in the performance of a power plant.

This article presents the problems experienced in a CSP Solar Power Plant, due to damages in the regeneration system, and how they dragged down the productivity of the plant.

Performance & Regeneration

Solar power plants operate on the principles of fluid mechanic and thermodynamic. The core value of any system design is the mass & heat balance, which subsequently stands as the building blocks of the performance model.

The performance model is conceived to identify the most significant aspects of the way in which a solar plant operates under ideal conditions. The results are used as a reference for running the plant as close as possible to that theoretical model. Along this line, we can identify divergencies, understand the way a solar plant functions and enhance the overall efficiency of the plant.

The overall efficiency depends on the performance of each individual system, and in this regard, regeneration plays an important role. The idea behind regeneration is to increase the thermal efficiency of the plant by raising the feedwater temperature before it enters the Solar Steam Generator (SSG). The process is accomplished in the so-called feedwater heaters where water is heated with bleed steam extracted from different stages of the turbine at given thermal conditions.

Regeneration decreases the thermal input required, reduces the gradient of enthalpy in the SSG, minimizes the risk of thermal shock in the preheater and increases the overall efficiency. Therefore, any possible departure from the expected operation of the regeneration system, will directly drag down the productivity of the plant.

That was the case experienced in a CCP solar power plant due to severe failure in the feedwater heaters during commissioning.

Process Description

The design of the plant incorporates parabolic through technology to capture solar energy in a heat transfer fluid (HTF). The HTF is sent to the solar steam generator (SSG) to exchange its enthalpy with high quality water to produce superheated steam. The process is carried out in a counter-current flow scheme, so hot oil produces superheated steam, then boils the water in the evaporators and finally, preheats the water in the economizer unit. The efficiency of the heat transfer depends on the water inlet temperature at this point of the system.

Eventually, the superheated steam is admitted to a steam turbine which exhausts the load to a surface condenser. The hotwell section serves as a water reservoir from where the condensate is pumped back to the cycle.

Now is when Regeneration takes place. A battery of heat exchangers set in a cascade configuration, are employed to rise the temperature of the water up to the steam generator economizer inlet. As depicted in figure 1, H3 and H4 are low pressure heat exchangers whereas H1 and H2 are designed for high-pressure. All of them are shell-tube type. Water flows through the tube side of the unit, while bleed steam is condensing in the shell side (black dash line). DA represents the deaerator, which is a direct mixing exchanger designed for removal of oxygen, CO2 and volatile impurities.

Failures in the Regeneration System

Operating anomalies were observed in the functionality of the feedwater heaters H1 and H2 throughout the first months of operation. A gradual decrease in their thermal performance brought the appearance of collateral problems which ended up affecting the total efficiency of the cycle. Therefore, a failure investigation was conducted to find out the root-cause of the problem and implement corrective actions to improve its performance.

The results of the analysis determined that these heaters got affected during the commissioning of the project. Both units were included in the scope of chemical cleaning and initial flushing, though, poor actions were taken to preserve their integrity during the execution of the activities. As a result, the second heater H2 acted as a real filter and a great deal of metal debris got blocked in most of the tubes. In view of the severe damage and leakages, this unit had to be replaced one year later.

Image 1 shows the frontal tube sheet of the second feedwater heater (H2). There were found uncountable numbers of eroded fragments of metals, welding slags, and stones embedded in the tubes. More than 55% of the tube bundle got permanently clogged.

The problem was detected due to a significant overconsumption in the feedwater pumps. Friction losses through the heaters may cause restriction of the water flow, and pumps need to increase speed to overcome the pressure drop. This could bring pumps to run beyond the allowable operating range which intensely reduces their efficiency. In a more extreme scenario, if the situation persists, the temperature reached in the pump could bring the water to its boiling point and cause more serious problems like cavitation, vibrations or mechanical failures in the rotating components.

The presence of metal debris in the heaters and the material incompatibility with the tubes favored the appearance of several types of corrosion attack. Subsequently, some them started to leak. Since pressure in the water side is around 80-100 bars greater than in the steam side, the mass of water passing to the shell side was enough to reduce the temperature of steam several degrees. This made the heat transfer not only less effective but also reduced the pressure in the deaerator. As a consequence, the quality of the water may be affected.

In any case, all of these instabilities forced opening the H2 manual bypass and leaving the heater out of service.

Bypassing H2 implied a temperature drop of 25ºC on average at the preheater inlet. The loss of enthalpy can be compensated by putting in solar tracking additional CCP mirrors. This action will concentrate more energy and increase the flow of HTF.

However, the problem went unseen for the first months of operation because, as it pertains to the process design, heaters H1 and H2 would remain out of service or in intermittent operation during summer operating mode. Thus, the 1st and 2nd extractions would be closed for the turbine to gain an extra flow of steam, and so, increase the production in 5% of the nominal gross. During winter, the maximum yield of the plant is achieved by using the total solar field, therefore, there would not be additional availability of solar field to mitigate the fall of temperature in the water side. So, the plant was forced to accept a loss of efficiency.

The problem in the feedwater heaters brought one further issue which also affected the performance of the plant which is depicted in Figure 3. Since the preheater inlet temperature is lower, and there is not extra heat input from the turbine extractions, the SSG would take longer to achieve its operating nominal point during the daily startup. By the same token, there was a loss of intertia on daily shutdown.

Conclusions

Commissioning is likely the most critical stage in the life time of a power plant due to the transient conditions which systems and equipment are exposed to. The total efficiency of the plant depends on the functionality of all of them.

Thus, any failure in design and execution of field activities have the potential to damage critical equipment and cause deviations in their expected performance. This may represent a significant impact in the overall performance of the plant. Therefore, it is advised to carry out continuous inspections, comprehensive monitoring of each system during the start-up of the plant, especially, develop Hazard and Operability Analysis plan for critical commissioning activities.

Refer to the following post to find extra information about this type of failure, click here

Commissioning

Acid Cleaning Corrosion

Acid Cleaning Corrosion

Background

Acid cleaning corrosion is a key factor to considering during the chemical cleaning activities. A few months after the completion of a combined cycle, the plant was forced to shut down due to operational instabilities and loss of pressure in the steam generator.

An exhaustive inspection was conducted to find out multiple leaks in the tube side of the evaporator and an uncommon yellowish pigment at the bottom header.  Some tube samples were taken and sent to laboratory to determine the metal morphology, surface chemical composition and the nature of the deposit.

Analysis

  • The spectroscopy X-ray results indicated the presence of a significant enrichment of carbon along with bonded oxygen and ferrous ions which suggests the presence of organic compounds.
  • X-ray diffraction revealed that most of the carbon and oxygen were combined in an aliphatic structure, suggesting the existence of citrates, which would explain the yellowish aspect.
  • The microscopy analysis showed an acid corrosion pattern with jagged, roughness, undercut pinholes and general pitting appearance

Conclusions

During pre-commissioning, the cleaning of the boiler was carried out by the execution of a traditional one-phase citric cleaning.

Throughout the acid pickling, citric acid bonds to iron oxide to form ferrous citrate which precipitates in the form of solid salt and it is afterward removed from the system in subsequent cleaning steps.

In this case, the system was not effectively washed out after the chemical cleaning, and great amount of deposits, with high content of ferrous citrate remained, in the evaporator.

The ferrous citrate, in combination with remaining water, created under deposit cells and regions of low pH which generated the corrosion damage shown in the photo.

 

Commissioning

Precommissioning Problems

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Commissioning

Target Plate Impacts

Target Plate Impacts

Consulting About Steam Blowing

A few days ago, we were consulted about a very interesting case that I would like to share my opinion as it would be useful for engineers involved with commissioning:

Can carryovers and/or water droplets affect the target plate during steam blowing?

Yes indeed. Carryovers can affect final results, specifically magnetite particles in the outer oxide layer that are not consistently attached to the surface and are driven off the drum.

Solution

This can be solved running the boiler at high pressure for a few days right before steam blowing starts, to allow steel increasing thickness, degree of compaction and hardness of the protective layer.

However, there are other few factors that may contribute to this happening and should be avoided, for instance, intermittent decompressions, chemical instabilities, defective chemical cleaning, insufficient blowdowns, operation with high level in the drum or low steam quality, among other deficiencies. Water droplets can also be a source of impingement and produce false reading of the pipe cleanliness.

For this purpose, it is recommended to place the target upstream temporary desuperheaters, prevent drains from clogging that can overflow driplegs and get dragged by steam, and finally make sure to get rid of all condensation during warmup stage.

target plate
Commissioning

Kraft Recovery Boilers

Kraft Recovery Boilers

Be Aware Of...

The Kraft process is a conversion reaction in which wood chips are digested in a batch reactor, at high alkaline water solution of NaOH and Na2S, to break up the lignin that holds the wood fibers together while obtaining almost pure cellulose, the main component of paper.

The waste stream produced from this industrial process is an aqueous black slurry, which contains great heat value due to its significant organic content, mainly, lignin and aliphatic carboxylic acids. The residual is dried in a multiple-effects evaporator to increase its solid content up to about 75% in weight.

Then, this concentrated slurry is atomized and combusted in Kraft Recovery Boiler to produce steam for self-consumption or electricity generation. However, the residual is also composed of inorganic species, including Na, K, S, Cl and C.

These elements are volatilized in the furnace of the boiler, where many complex reaction mechanisms occur at different air levels, producing a great variety of chemical compounds such as Na2SO4, KCl, K2SO4 and Na2CO3. All of them are carried in the flue gases as fly ashes.

Here is the bad thing…carryover particles deposit in the front and backside of the superheaters causing rock-like formations that can block the entire unit and cause devastating consequences. The effects are shown in the below picture, which I took in an inspection during a shutdown.

Kraft Process
Kraft process 2
Commissioning

Steam Blowing Insights

Some Insights About Steam Blowing

Introduction

The science behind steam blowing involves the optimization of the drag force of the steam and the chemical conditioning for corrosion control.

Fludization Aspects
The fluidization potential (drag force) can be enhanced by minimizing the boundary layer thickness of the fluid, all along the surface of the pipe, as follow:

1.  Running at high Reynolds will increase turbulences, adjust the velocity profile and boost terminal velocity near the surface.
2.  Rising temperature will reduce the viscous layer, and so, the shear wall stress.
3. Increasing density will maximize the momentum (kg/m·s2) of the steam. This can be done by injecting water in the superheater outlet to blow with saturated steam.

Chemical Aspects
Chemistry also plays an essential role in the performance of steam blowing. The dynamic nature of this operation makes impossible to control carryovers, deposition of salts, oxides formation and diffusion of impurities. Shutdown periods for thermal cycles can also increase the concentration of O2 in the boundary layer. As a result, corrosion can be quite active during these stage of commissioning.

Suggestions

As suggestion, it is recommended to first carry out a chemical cleaning in the steam system. Then, start-up the steam generator for a few days to improve chemistry conditioning. Finally, proceed with the execution of steam blowing.

boundary layer
Commissioning

Common Boiler Deposits

Common Boiler Deposits

Description

Deposition in power plants is most likely the least understood aspect of the operational cycle chemistry applicable to these units during commissioning. Having a complete understanding of the subject is a key factor for the performance of an effective chemical cleaning and the chemical treatment program to be applied. This will represent the fundamental building blocks for the success of the steam conditioning process and further reliability of the chemistry cycle during operation.

For this matter, knowing the nature of the deposit is of significant importance aspect to take into consideration. Most prevalent deposits compounds found in power plants are corrosion products of iron oxides, cooper oxides and derivatives formed as a result of lack of conservation during construction, improper preservation procedures, and deficient water treatment programs.
The following table lists crystalline compounds and other materials that have been observed in water formed deposits of steam generation equipment

Commissioning

Ineffective Cleaning?

Ineffective Chemical Cleaning?

Introduction

Ineffective chemical cleaning? Not really… we have encountered situations where engineers and operators complaint about the cleanliness of the boiler as they see a black liquid coming off the blowdown system during first fire.

It´s not difficult to get carried away by a first impression and put into question the effectiveness of the chemical cleaning.

Explanations

This dark watery constituent is in reality a very welcome natural corrosion-protection product called Magnetite and it is formed as the steel surface is exposed to water under certain conditions.

The formation of Magnetite is an electrochemical process controlled by a continuous diffusion of iron ions from the steel surface across the water boundary layer and its stability, morphology and porosity depends on the oxidation-reduction potential, pH, oxygen concentration, pressure, temperature and the influence of the make-up water chemistry (CO2, Cl, Si, Na, Ca, Mg…)

Solubility rises with temperature up to 150ºC, then decreases with a steep drop to 300°C. Pressure promotes the growth of magnetite and thickness Having said that, the reason of the dark appearance of the blowdown during a boiler ramp-up is mainly due to the deposition of low quality magnetite since steady conditions has not been reached yet.

magnetite
Commissioning

Chromatic Changes

Chromatic Changes

Recommendation

Chromatic interactions are a great indicator of the kinetic and chemical reaction throughout the course of a chemical cleaning.

It is of significant importance to collect samples from different part of the system during the treatment operation as color changes provide reliable information about the evolution of the reaction taking place.

Explanation

Inhibitive effects of sodium nitrite (among other passivation agents) are accepted due to the oxidation of Fe2+ ion to form a very thin layer (40-100 armstrongs) of gamma-Fe2O3 on the piping inner surface under alkaline solutions.
The color of this final compound is black or brownish-black and along with the redox potential measurement will determine the completion of the process.

The picture below displays from left to right color changes in all stages of an HF acid treatment methodology.

chromatic changes
Commissioning

Travelling Across Boiler Tube

Travelling Across A Boiler Tube

Ready for an amazing journey?

Take a minute to travel across a preheater boiler tube affected with severe under deposit corrosion and overall oxygen pitting at early stages of development. This journey shall help you to become aware of the importance of having a deep understanding of the natural chemical reactions involved in a power plant. Only this way you will be able to identify potential failures and take proactive actions. In this particular case, the internal corrosion pattern in the tube is mainly due to the effect of high dissolved oxygen concentration in the presence of excessive non-volatile constituents in the quality of the make-up water. Enjoy!!   click here

Boiler Tube

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